| S.no | Portfolio | Name |
|---|
| 1 | Prime Minister, who is also In-Charge of Ministries/Departments viz: | Manmohan Singh |
| Minister of Atomic Energy |
| Minister of Space |
| Minister of Personnel, Public Grievances and Pensions |
| Ministry of Planning |
| 2 | Minister of Defence | A. K. Antony |
| 3 | Minister of Agriculture | Shri Sharad Chandra Govindrao Pawar |
| Minister of Food Processing Industries |
| 4 | Minister of Finance | P. Chidambaram |
| 5 | Minister of External Affairs | Salman Khurshid |
| 6 | Minister of Home Affairs | Sushil Kumar Shinde |
| 7 | Minister of Communications and Information Technology | Kapil Sibal |
| 8 | Minister of Human Resource Development | Dr. Pallam Raju |
| 9 | Minister of Law and Justice | Ashwani Kumar |
| 10 | Minister of Chemicals and Fertilizers | M. K. Alagiri (Resigned on 21st March 2013) |
| 11 | Minister of Civil Aviation | Ajit Singh |
| 12 | Ministry of Mines | Shri Dinsha J. Patel |
| 13 | Minister of Commerce and Industry | Anand Sharma |
| Minister of Textiles |
| 14 | Minister of Petroleum and Natural Gas | Veerappa Moily |
| 15 | Minister of Culture | Chandresh Kumari Katoch |
| 16 | Minister of Housing and Urban Poverty Alleviation | Ajay Maken |
| 17 | Minister of Water Resources | Harish Rawat |
| 18 | Minister of Rural Development | Jairam Ramesh |
| 19 | Minister of Urban Development | Kamal Nath |
| Minister of Parliamentary Affairs |
| 20 | Minister of Overseas Indian Affairs | Vayalar Ravi |
| 21 | Minister of Health and Family Welfare | Ghulam Nabi Azad |
| 22 | Minister of Heavy Industries and Public Enterprises | Praful Manoharbhai Patel |
| 23 | Minister of Labour and Employment | Mallikarjun Kharge |
| 24 | Minister of New and Renewable Energy | Farooq Abdullah |
| 25 | Minister of Panchayati Raj | Kishore Chandra Deo |
| Minister of Tribal Affairs |
| 26 | Minister of Railways | Pawan Kumar Bansal |
| 27 | Minister of Science and Technology | Jaipal Reddy |
| Minister of Earth Sciences |
| 28 | Ministry of Coal | Sri Prakash Jaiswal |
| 29 | Minister of Road Transport and Highways | Dr. C. P. Joshi |
| 30 | Minister of Shipping | G. K. Vasan |
| 31 | Ministry of Social Justice and Empowerment | Selja Kumari |
| 32 | Minister of Steel | Beni Prasad Verma |
| 33 | Minister of Minority Affairs | K. Rahman Khan |
| Ministers of State with Independent Charge |
| 1 | Ministry of Information and Broadcasting | Manish Tewari |
| 2 | Ministry of Power | Jyotiraditya Madhavrao Scindia |
| 3 | Ministry of Drinking Water and Sanitation | Bharatsinh Madhavsinh Solanki |
| 4 | Ministry of Youth Affairs and Sports | Jitendra Singh |
| 5 | Ministry of Corporate Affairs | Sachin Pilot |
| 6 | Ministry of Women and Child Development | Krishna Tirath |
| 7 | Ministry of Consumer Affairs, Food and Public Distribution | Prof. K. V. Thomas |
| 8 | Ministry of Statistics and Programme Implementation | Srikant Kumar Jena |
| 9 | Ministry of Environment and Forests | Jayanthi Natarajan |
| 10 | Ministry of Development of North Eastern Region | Paban Singh Ghatowar |
| 11 | Ministry of Micro, Small and Medium Enterprises | K. H. Muniyappa |
| 12 | Ministry of Tourism | Chiranjeevi (Konidala Siva Sankara Vara Prasad) |
| Ministers of State |
| 1 | Ministry of External Affairs | Shri E. Ahamed |
| 2 | Ministry of Defence | Shri Jitendra Singh |
| 3 | Ministry of Commerce and Industry | Shri S. Jagathrakshakan (Resigned on 21st March 2013) |
| 4 | Ministry of Labour and Employment | Shri Suresh Kodikunnil |
| 5 | Ministry of Chemicals and Fertilizers | Shri Srikant Kumar Jena |
| 6 | Ministry of Rural Development | Shri Lalchand Kataria |
| 7 | Ministry of Parliamentary Affairs | Shri Paban Singh Ghatowar |
| 8 | Ministry of Urban Development | Smt. Deepa Dasmunsi |
| 9 | Ministry of Health and Family Welfare | Shri S. Gandhiselvan (Resigned on 21st March 2013) |
| 10 | Ministry of Social Justice and Empowerment | Shri D. Napoleon (Resigned on 21st March 2013) |
| 11 | Ministry of Civil Aviation | Shri K. C. Venugopal |
| 12 | Ministry of Human Resource Development | Shri Jitin Prasada |
| 13 | Ministry of Human Resource Development | Dr. Shashi Tharoor |
| 14 | Ministry of Home Affairs | Shri Ramachandran Mullappally |
| 15 | Prime Minister Office Ministry of Personnel, Public Grievances and Pensions | Shri V. Narayanasamy |
| 16 | Ministry of Commerce and Industry | Smt. Daggubati Purandeswari |
| 17 | Ministry of Railways | Shri Adhir Ranjan Chowdhury |
| 18 | Ministry of Railways | Shri Kotla Jaya Surya Prakash Reddy |
| 19 | Ministry of Petroleum, Natural Gas and Ministry of Textiles | Smt. Lakshmi Panabaka |
| 20 | Ministry of Finance | Shri Namo Narain Meena |
| 21 | Ministry of Finance | Shri S.S. Palanimanickam (Resigned on 21st March 2013) |
| 22 | Ministry of Road Transport and Highways | Shri Sathyanarayana Sarvey |
| 23 | Ministry of External Affairs | Smt. Preneet Kaur |
| 24 | Ministry of Agriculture, Ministry of Food Processing Industries | Dr. Charan Das Mahant |
| 25 | Ministry of Agriculture and Ministry of Food Processing Industries | Shri Tariq Anwar |
| 26 | Ministry of Tribal Affairs | Smt. Ranee Narah |
| 27 | Ministry of Social Justice and Empowerment | Shri Porika Balram Naik |
| 28 | Ministry of Health and Family Welfare | Shri Abu Hasem Khan Choudhury |
| 29 | Ministry of Parliamentary Affairs and Ministry of Planning | Shri Rajeev Shukla |
| 30 | Ministry of Road Transport and Highways | Dr. Tushar Amarsinh Chaudhary |
| 31 | Ministry of Communications and Information Technology and Ministry of Shipping | Shri Milind Murli Deora |
| 32 | Ministry of Communications and Information Technology | Dr. (Smt.) Kruparani Killi |
| 33 | Ministry of Coal | Shri Pratik Prakashbapu Patil |
| 34 | Ministry of Minority Affairs | Shri Ninong Ering |
| 35 | Ministry of Rural Development | Shri Pradeep Kumar Jain Aditya |
| 36 | Ministry of Home Affairs | Shri Ratanjit Pratap Narain Singh |
